High Performance Fiber Research Articles

Hydrophobic Silk Fibroin–Agarose Composite Aerogel Fibers with Elasticity for Thermal Insulation Applications

Aerogel fibers, characterized by their ultra-low density and ultra-low thermal conductivity, are an ideal candidate for personal thermal management as they hold the potential to effectively reduce the energy consumption of room heating and significantly contribute to energy conservation. However, most aerogel fibers have weak mechanical properties or require complex manufacturing processes. In this study, simple continuous silk fibroin–agarose composite aerogel fibers (SCAFs) were prepared by mixing agarose with silk fibroin through wet spinning and rapid gelation, followed by solvent replacement and supercritical carbon dioxide treatment. Among them, the rapid gelation of the SCAFs was achieved using agarose physical methods with heat-reversible gel properties, simplifying the preparation process. Hydrophobic silk fibroin–agarose composite aerogel fibers (HSCAFs) were prepared using a simple chemical vapor deposition (CVD) method. After CVD, the HSCAFs’ gel skeletons were uniformly coated with a silica layer containing methyl groups, endowing them with outstanding radial elasticity. Moreover, the HSCAFs exhibited low density (≤0.153 g/cm3), a large specific surface area (≥254.0 m2/g), high porosity (91.1–94.7%), and excellent hydrophobicity (a water contact angle of 136.8°). More importantly, they showed excellent thermal insulation performance in low-temperature (−60 °C) or high-temperature (140 °C) environments. The designed HSCAFs may provide a new approach for the preparation of high-performance aerogel fibers for personal thermal management.

Comprehensive Analysis of Mechanical, Economic, and Environmental Characteristics of Hybrid PE/PP Fiber-Reinforced Engineered Geopolymer Composites

Engineered Geopolymer Composites (EGCs), known for their excellent tensile properties and lower carbon emissions, have gained widespread attention in the field of fiber-reinforced concrete. However, the high cost of high-performance synthetic fibers, a crucial component of EGCs, limits their practical engineering applications. In this study, by using low-cost PP fibers hybridized with PE fibers and adjusting the fly ash/ground granulated blast furnace slag (FA/GGBS) ratio, cost-effective, high-performing hybrid PE/PP-reinforced engineered geopolymer composites (H-EGCs) were developed. This study conducted axial compressive and tensile tests on H-EGCs with different FA/GGBS ratios (7:3, 6:4, and 5:5) and PP fiber replacement ratios (0%, 25%, 50%, 75%, and 100%), investigated the influence of FA/GGBS and PP fiber replacement ratio on static mechanical behavior, and evaluated the economic and environmental benefits based on mechanical performance indicators. The result indicated that the compressive strength of H-EGCs can reach 120 MPa when the FA/GGBS ratio is 5:5; however, an increase in FA/GGBS and PP fiber replacement ratio leads to a loss in compressive strength and elastic modulus. The incorporation of PP fibers in moderate amounts enhances ultimate tensile strain by reducing crack control ability, and the maximum tensile deformation capacity (7.82–9.66%) was obtained for H-EGCs with a PP fiber replacement ratio of 50%. The optimal economic and environmental benefits of H-EGCs are observed when the FA/GGBS ratio is 5:5 and the PP fiber replacement ratio is set at 50%.

Mechanical Behaviour of As-Manufactured and Repaired Aligned Discontinuous Basalt Fibre-Reinforced Vitrimer Composites

The aim of this research is to investigate basalt as a natural mineral-based fibre together with a vitrimeric resin as a sustainable alternative to standard composite materials. Vitrimers combine the properties of thermoset and thermoplastic polymers, enabling the repair of specimens and hence prolonging the lifetime of the composite material. The micro-mechanical characteristics between the basalt fibres and the vitrimer resin are reported and shown to match those of a standard Skyflex K51 epoxy resin. Discontinuous (4 mm) basalt fibres were employed to produce aligned discontinuous fibre-reinforced composites (ADFRCs) using the high-performance discontinuous fibre (HiPerDiF) technology. The mechanical characteristics of the laminates were investigated through tensile testing and the fracture zones were analysed under a scanning electron microscope. By normalising the results by their respective fibre volume fraction, it was discovered that the vitrimer–basalt ADFRCs exhibited, on average, a 4% higher strength and a 25% higher stiffness compared to their basalt epoxy counterparts. The repair potential of the vitrimer ADFRC specimens was explored during low-temperature compression repair. Two approaches were tested using double-sided local- and full-patch repair. Both successfully recovered a significant amount of their prime strength. In conclusion, the potential of the sustainable vitrimer–basalt composite is shown by its competitive mechanical performance. Combining this with the manufacturing flexibility, repair potential, and recyclability of the material, the vitrimer–basalt composite seems to be a competitive alternative to standard glass epoxies.

A multiscale experimental study of CFRP-UHPFRC interfacial bond behaviour: Failure mechanisms and a fibre volume dependent bond-slip law

Carbon fiber reinforced polymer (CFRP) materials are being increasingly used with ultra high performance fiber reinforced concrete (UHPFRC) to construct composite structural members making use of their unique properties. As the interfacial bond behaviour between CFRP and UHPFRC plays a key role in the design of such members, it was investigated in detail by multiscale experiments of single shear pull-off tests of 26 CFRP-UHPFRC bonded joints with different bond lengths and widths of CFRP laminates and 0.5–4% volume fraction (Vsf) of straight high-strength steel fibers (length = 13 mm, diameter = 0.2 mm). 12 CFRP-normal strength concrete (NSC) bonded joints were also tested for comparison. The surface strain evolution and the interfacial debonding process were captured and analysed by the digital image correlation (DIC). The complex microscale failure mechanisms, such as the mortar cracking, the CFRP-UHPFRC interfacial debonding, and the steel fibers’ slipping and pulling out of the mortar, were visualised and analysed by the 3D micro X-ray Computed Tomography (μXCT) scanning. It was found that the debonded layer of mortar under the laminates was much thinner than that in the CFRP-NSC bonded joints, due to the lack of coarse aggregates in UHPFRC. The peak pulling forces for the specimens with Vsf = 0.5%, 1%, 2%, and 4% were 9%, 21%, 28%, and 29% higher than those without steel fibers, respectively. An empirical bond strength model and an interfacial bond-slip model were proposed based on the test results, accounting for Vsf, the material properties, and the laminate to UHPFRC width ratio. Finally, the proposed bond-slip model was applied in finite element modelling to simulate the flexural behaviour of an FRP-UHPFRC composite deck in the literature, with the interfacial debonding failure and the ultimate loads successfully predicted.

Polymer Physics Behind the Gel-spinning of UHMWPE Fibers.

Gel-spinning of ultra-high molecular weight polyethylene (UHMWPE) fibers has attracted great interest in academia and industry since its birth and commercialization in the 1980s, due to unique properties such as high modulus, low density, and excellent chemical resistance. However, the high viscosity and long relaxation time greatly complicate processing. In industry, solvents like decalin, paraffin oil, etc., usually disentangle the physical networks and promote final drawability. From extruding the polymer solution to post-solid-stretching, many polymer physics problems that accompany high-modulus fiber gel-spinning should be understood and addressed. In this review, by detailed discussions about the effect of entanglements and intracrystalline chain dynamics on the mechanical properties of UHMWPE, we provide theoretical descriptions of the structure formation of disentangled UHMWPE crystals and the origin of high modulus and strength of final fibers. Several physical intrinsic key factors are also discussed, revealing why UHMWPE is an ideal material for producing high-performance fibers. This article is protected by copyright. All rights reserved.

Improved Plating Adhesion of Polyarylate Fibers via Supercritical CO2 and Impregnation of Slightly Soluble Oil on the Fiber Surface

AbstractThere is a growing demand for conductive fibers with high bending resistance, particularly for applications, such as smart textiles and robot arms. The amount of fiber for such applications can be reduced using high-performance fibers with high tensile properties, such as polyaramid and polyarylate Vectran®). However, because such fibers are crystalline with rigid molecular structures, they poorly adhere to plated films; thus, the plated fibers exhibit poor bending fatigue resistance. To solve this problem, in this study, we expanded polyarylate fiber using supercritical CO2 (ScCO2) and impregnated it with a metal complex (palladium acetate), which acts as a catalyst for electroless plating to induce an anchoring effect. However, because polyarylate fiber has an extremely low polarity, it is difficult to uniformly impregnate it with many metal complexes, even with ScCO2. Generally, an organic solvent is added to tune the polarity of supercritical CO2; however, the metal complex penetrates the fiber, thereby reducing the amount of metal complex near the fiber surface. Therefore, we tuned the polarity of the surface by applying various oils to the fiber surface. The sample electroplated in ScCO2 with oil applied to its surface showed the highest bending fatigue resistance, followed by that treated in ScCO2 without oil, and the sample treated in an aqueous solution showed the lowest. Furthermore, we measured the interfacial adhesion strength of the samples using the microdroplet method, and the same trend was observed.

Kinetic Modulation of Carbon Nanotube Growth in Direct Spinning for High-Strength Carbon Nanotube Fibers.

With impressive individual properties, carbon nanotubes (CNTs) show great potential in constructing high-performance fibers. However, the tensile strength of as-prepared carbon nanotube fibers (CNTFs) by floating catalyst chemical vapor deposition (FCCVD) is plagued by the weak intertube interaction between the essential CNTs. Here, we developed a chlorine (Cl)/water (H2O)-assisted length furtherance FCCVD (CALF-FCCVD) method to modulate the intertube interaction of CNTs and enhance the mechanical strength of macroscopic fibers. The CNTs acquired by the CALF-FCCVD method show an improvement of 731% in length compared to that by the conventional iron-based FCCVD system. Moreover, CNTFs prepared by CALF-FCCVD spinning exhibit a high tensile strength of 5.27 ± 0.27 GPa (4.62 ± 0.24 N/tex) and reach up to 5.61 GPa (4.92 N/tex), which outperforms most previously reported results. Experimental measurements and density functional theory calculations show that Cl and H2O play a crucial role in the furtherance of CNT growth. Cl released from the decomposition of methylene dichloride greatly accelerates the growth of the CNTs; H2O can remove amorphous carbon on the floating catalysts to extend their lifetime, which further modulates the growth kinetics and improves the purity of the as-prepared fibers. Our design of the CALF-FCCVD platform offers a powerful way to tune CNT growth kinetics in direct spinning toward high-strength CNTFs.

Effect of isopropyl chloride addition in AlCl3 catalytic system on the formation of coal tar pitch-based mesophases

Mesophase pitch is a high-quality precursor for the synthesis of high-performance pitch-based carbon fibers. The mesophase content, texture and softening point are the most important factors for the structure, properties and spinnability of mesophase pitch (MP). Herein, we report a novel approach for the preparation of mesophase pitch with high anisotropic content and low softening point by AlCl3 catalytic pyrolysis in the presence of isopropyl chloride (PrCl). The variation of anisotropic content and mesophase texture under different PrCl additions and the effect of the introduction of isopropyl on the molecular stacking of aromatic lamellar molecules were investigated. The results confirmed that, except for their role in improving catalytic activity, carbocation co-catalysts can improve the structure and molecular assembly of aromatic molecules through the introduction of alkyl groups. The reaction of isopropyl chloride (PrCl) as a co-catalyst catalyzed pyrolysis of medium-temperature coal pitch at 370 ℃ for 8h produced a bulk mesophase with a content close to 100%. Compared to the AlCl3 system (without PrCl), the AlCl3-PrCl system can catalyze the preparation of mesophases at lower temperatures. In addition, it is logical that the introduction of isopropyl group significantly increases the stacking spacing of the mesophase pitch layer molecules, which can effectively improve the mobility of the aromatic layer molecules resulting in the growth of mesophase. The fusion texture and anisotropic content of mesophase pitch were significantly improved by replacing the nucleophilic reagent of the AlCl3-catalyzed system. This work provides feasible ideas for the preparation of high-performance coal tar based mesophase pitch.

High Performance and Ultra-High Performace Fibre Reinforced Concrete with Stabilized Homogeneity

This paper describes the segregation of fibres in high performance and high strength concretes. It focuses on both laboratory and practical conditions. It compares different mixtures produced and processed in the laboratory and in the precast concrete company. Two methods are chosen in the paper to avoid fibre segregation. The first method is a suitable mix design considering the water/cement ratio and the amount of superplasticizer. The second method is the addition of synthetic fibres to the mixture while maintaining sufficient workability. The paper examines the consistence of each mixture according to the concrete placement location, segregation of fibres in the fresh mixture and hardened composite. Both methods under laboratory and practical conditions have shown a positive impact on the reduction of segregation of steel fibres in the mixture. Simultaneously, the strength properties of all mixtures were compared, which depended mainly on the type of synthetic fibres used.

A study on aramid nano-aerogel fiber and its fabric thermal conductivity

Aramid nano-aerogel represents an ideal structure for the fabrication of next-generation high-performance thermal insulation fibers and textiles. Single aramid nano-aerogel fiber can be achieved via wet spinning. The thermal conductivity of these fibers, a crucial determinant of textile insulation performance, remains under-explored in terms of numerical modeling. This research aims to establish a numerical inversion model to determine the thermal conductivity of single aramid nano-aerogel fiber. By simulating the three-dimensional geometry of plain fabric, the volume fraction of gas and solid within the fabrics are computed. Drawing from the law of energy conservation and Fourier's law of heat conduction, a relationship model is proposed between the thermal conductivity of single aramid nano-aerogel fiber and the overall thermal conductivity of the fabric. The finite difference method is employed to ascertain the thermal conductivity of single aramid nano-aerogel fiber. Furthermore, the influence of the geometric structure and the fiber diameter on the thermal insulation performance of the single-layer fabric is analyzed, which provides a feasible approach for the subsequent design of fabric structures with excellent thermal insulation properties.

High-performance Fabry-Perot fiber optic sensors from one-step laser side-polished platforms

A facile one-step non-contact process was developed for preparing the substrates for Fabry-Perot-based side-polished optical fiber sensors. A carbon dioxide (CO2) laser cladding removal technique was used to control the profile of the polished fiber surface and to introduce two reflective cavities. The substrates were characterized for a range of cavity lengths and their thermal response was studied. This device added a degree of freedom to the design of optical fiber based Fabry-Perot sensors and its potential was demonstrated by coating the substrate with polydimethylsiloxane (PDMS). The resulting sensors had a three-order of magnitude increase in sensitivity when compared to the substrate. The polished flat surface provided a route for the integration of novel materials for sensing applications, particularly those where polarization control was vital for light-matter interaction, for example, low dimensional materials such as graphene or MXene. The inherent simplicity, mechanical stability, and scalability of this approach are important steps for the realization of practical devices of this type.

Cumulative energy demand analysis in the current manufacturing and end-of-life strategies for a polymeric composite at different fibre-matrix combinations

Fibre Reinforced Polymers (FRPs) are finding more applications in different industrial sectors. From a sustainability point of view, a component made of FRPs reduces energy consumption and CO2 emissions during its use-phase due to the material's lightweight nature. However, the production of these materials impacts the global energy demand significantly. To mitigate this impact, circular economy strategies are essential. This study focuses on a Cumulative Energy Demand (CED) analysis for different End-of-Life (EoL) strategies of FRPs components. Three EoL routes were evaluated: i.e., combustion, recycling and reforming of continuous fibres reinforced thermoplastics. Different fibres and matrices and three Fibre Volume Fractions (FVF) were taken into account. Specifically, Glass Fibres, Carbon Fibres, Polypropylene, and Polyether ether ketone were examined while FVF of 11%, 23% and 45% were evaluated. A Life Cycle Inventory data was built combining literature review and CES Edupack database. The results provided some guidelines for optimising the product's EoL phase in terms of CED reduction underlining the advantages and high competitiveness of the reforming strategy especially if high-performance matrices and/or fibres are processed. Recycling results to be a valuable EoL alternative if FRPs made by high-performance fibres and high FVF are employed while combustion is the more advisable option if low-performance matrices and fibres are used.

A versatile dyeing approach for the high-performance fibers via surface modification of silane coupling agents

The inert surface and high degree of crystallinity make it difficult for the coloration for the high-performance filaments. In this work, inspired by the amphipathic character of the silane coupling agent (KH570), it has been employed as an intermediary to connect the dyes and the filaments. Under a series of modification pH values, KH570 binding layer exhibits different performance on the filament surface. Combining several characterizations, it is suggested that at pH of 12, the condensed molecules grow to the colloidal particle size, endowing the modification solution with special viscosity character. Due to the lack of hydroxyl groups on the filaments surface, KH570 molecules cling to the filament by this physical adhesive force. Therefore, a uniform coating layer of KH570 can be observed on the filaments surface under a modification condition of pH 12. As expected, the dyeing results show that the pH12-modified sample has the best dye affinity, with the K/S peak value significantly increased ∼11 times compared to the unmodified one. Eventually, this activation technique has been applied to several types of high-performance filaments, and significant enhancement is also obtained for the K/S value, demonstrating the versatility of such dyeing approach.

5G NB-IoT System Integrated with High-Performance Fiber Sensor Inspired by Cirrus and Spider Structures.

Real-time telemedicine detection can solve the problem of the shortage of public medical resources caused by the coming aging society. However, the development of such an integrated monitoring system is hampered by the need for high-performance sensors and the strict-requirement of long-distance signal transmission and reproduction. Here, a bionic crack-spring fiber sensor (CSFS) inspired by spider leg and cirrus whiskers for stretchable and weavable electronics is reported. Trans-scale conductive percolation networks of multilayer graphene around the surface of outer spring-like Polyethylene terephthalate (PET) fibers and printing Ag enable a high sensitivity of 28475.6 and broad sensing range over 250%. The electromechanical changes in different stretching stages are simulated by Comsol to explain the response mechanism. The CSFS is incorporated into the fabric and realized the human-machine interactions (HMIs) for robot control. Furthermore, the 5G Narrowband Internet of Things (NB-IoT) system is developed for human healthcare data collection, transmission, and reproduction together with the integration of the CSFS, illustrating the huge potential of the approach in human-machine communication interfaces and intelligent telemedicine rehabilitation and diagnosis monitoring.

Effect of Bonding Type on the Failure of Reinforced Concrete Beam Strengthened with In-Situ High Performance Fibre Reinforced Concrete Layer

High performance fibre reinforced concrete (HPFRC) materials with tensile hardening behaviour can effectively be used for strengthening reinforced concrete beams. A perfect bond between the original and the reinforcing layer cannot be formed, the load-bearing capacity and ductility of the strengthened beam can significantly be affected by the interfacial bond strength between the contacting surfaces. In this paper, beam retrofitting with cast in-situ strengthening type is examined. The purpose of this experimental study is to investigate the impact of the different bond types on the load-bearing capacity, ductility, and failure mode of the strengthened beams in the case of cast in-situ strengthening. Twenty-four beam tests were performed with untreated and rough surfaced beams, with or without connecting elements. The effect of the bond type proved to be significant regarding the failure mode in the case of compression side strengthening, stronger bond resulted in higher load bearing capacity and ductility, too. When tensile side reinforcement was investigated no average increment was experienced in the maximal force and ductility due to the stronger bond. Based on the results, it can be concluded that the generally applied analytical models that assume perfect connection may lead to exaggerated results in the case of a compressed side HPC-strengthened beam. Therefore, it is necessary to develop a model that considers the effect of the imperfect bond.

Theoretical calculation and experimental analysis on humidification performance of high-performance water-absorbing porous fiber plates

In order to improve the indoor relative humidity in winter, a high-performance water-absorbing porous fiber plate was introduced in this paper, which absorbed water and infiltrated through capillary action, and an experimental system with porous plates arranged in parallel as humidifying elements was designed and constructed to explore the humidifying performance of porous plates and to expand its application field. The experimental results showed that the humidification effect of porous plates was excellent. At a relative humidity of 15 %, mainstream air velocity of 3.5 m/s, and air temperature of 45 °C, the maximum humidification capacity of the system reached 266.4 g/h. The humidification capacity was proportional to the air temperature and mainstream air velocity, and inversely proportional to the relative humidity of the air. The mainstream air velocity increased by 0.5 m/s, the humidification capacity increased by about 20 g/h. The change trend of humidification capacity and heat transfer quantity calculated through the criterion correlation was consistent with the measured values, and the relative errors between the theoretical and experimental values for most of the conditions were within 20 %. One of the reasons for the errors might be that the mainstream air velocity in the gaps between the porous plates was greater than the mainstream air velocity of the experimental air duct used in the theoretical calculation. Due to the difficulty in measuring the air velocity in the gaps between porous plates, CFD simulations were conducted. The relative errors between the theoretical corrected values calculated with the simulated air velocities and the experimental values were within 10 % for most of the conditions, and between 10 % and 15 % for very few conditions.

Plastic deformation and strengthening mechanism in CoNiV medium-entropy alloy fiber

High/medium-entropy alloys (H/MEAs) are regarded as a potentially viable alternative to conventional metallic fibers for the production of ductile, high-strength fibers, to resolve the inherent trade-off between strength and ductility. The present study involved the cold drawing technique to produce a CoNiV MEA fiber measuring 300 μm in diameter with a length of more than 3 m. The mechanical properties of the FCC matrix can be improved through the inclusion of an appropriate amount of the κ phase via the optimized thermal treatment process. In addition to a yield strength of 1681 MPa and a well-coordinated elongation of 13.4 %, the ideal CoNiV fiber demonstrated a substantial ultimate tensile strength of 1932 MPa. Further calculations revealed that the κ phase, which possesses a substantial Von Mises stress of approximately 2715 MPa and an area fraction of 18.2 ± 1.1 %, was observed to be a primary contributor to the strength. Deformation twins were generated in the FCC matrix as a result of the ultra-high flow stress, which provided adequate ductility. This study offers significant contributions to the understanding of the deformation mechanisms and strengthening effect of the κ phase, thereby facilitating the development of high-performance metallic fibers.

Rigid-flexible coupling poly (phenylene sulfide) fiber membrane: a highly stable chemical and thermal material for energy and environmental applications

The poly (phenylene sulfide) (PPS) fiber membrane is composed of interwoven fibers, with a three-dimensional porous structure. The three-dimensional porous structure makes PPS fiber membranes have high porosity and large specific surface area, which stands out in the field of membrane separation. A PPS fiber is a high-performance fiber with excellent chemical and thermal stability. These characteristics allow PPS fiber membranes to be used in harsh membrane separation environments such as strong acids, alkalis, and high temperatures. However, the corrosion resistance and high-temperature stability of PPS fibers also make the preparation of PPS fibers and their membranes challenging. In this paper, the preparation method is summarized, including two direct methods to make a PPS fiber membrane: melt-blown spinning and melt electrostatic spinning, and two indirect methods: wet papermaking and weaving. Additionally, the applications of PPS fiber membranes are summarized in detail in energy and environmental fields, such as lithium-ion batteries, alkaline water electrolysis, air filtrations, chemical catalyst substrates, and oil-water separations. This review provides an insightful understanding of PPS fiber membrane preparation methods and the interconnections between these preparation methods and specific applications, thus laying a solid foundation for further advancing the range of PPS fiber membrane applications.

Scalable electrochemical grafting of anthraquinone for fabrication of multifunctional carbon fibers

Carbon fiber electrodes were prepared by grafting anthraquinone molecules via a scalable electrochemical approach which simultaneously increased interfacial and electrochemical capacitance properties. In this work, anthraquinone diazonium salts were synthesized and grafted onto carbon fiber tows at various concentrations. These modified fibers were subsequently evaluated mechanically and electrochemically to analyze their suitability in structural supercapacitors. Compared to control fibers, the grafted anthraquinone groups resulted in a 30% increase in interfacial shear strength (IFSS) and 6.6× increase in specific capacitance. Industry application was also a focus thus carbon fibers were also modified with in-situ generated diazonium salts to determine the applicability to an in-line industrial process. Specifically, potentiostatic functionalization of fibers with in-situ generated diazonium salts AQ-1 and AQ-2, showed 3× and 4.3× increase in specific capacitance, respectively, relative to unmodified carbon fiber (CF). We expect that implementing a scalable method to introduce a conductive and electrochemically active covalently bound surface chemistry layer onto carbon fiber exhibits a higher specific capacitance than carbon fiber grafted with most other small molecules reported in literature. This will open new avenues for manufacturing multifunctional and high-performance fibers with tailored properties for specific/targeted applications.

Modular Protein Fibers with Outstanding High-Strength and Acid-Resistance Performance Mediated by Copper Ion Binding and Imine Networking.

Engineered protein fibers are promising biomaterials with diverse applications due to their tunable protein structure and outstanding mechanical properties. However, it remains challenging at the molecular level to achieve satisfied mechanical properties and environmental tolerance simultaneously, especially under extreme acid conditions. Herein, the construction of artificial fibers comprising chimeric proteins made of rigid amyloid peptide and flexible cationic elastin-like protein (ELP) module is reported. The amyloid peptide readily assembles into highly organized β-sheet structures that can be further strengthened by the coordination of Cu2+ , while the flexible ELP module allows the formation of imine-based crosslinking networks. These double networks synergistically enhance the mechanical properties of the fibers, leading to a high tensile strength and toughness, overwhelming many reported recombinant spidroin fibers. Notably, the coordination of Cu2+ with serine residues could stabilize β-sheet structures in the fibers under acidic conditions, which makes the fibers robust against acid, thus enabling their successful utilization in gastric perforation suturing. This work highlights the customization of double networks at the molecular level to create tailored high-performance protein fibers for various application scenarios.